Prof. Ewoldt delivered a plenary lecture on “Design of Yield-Stress Fluids” at the 8th International Symposium on Food Rheology and Structure in Zürich, Switzerland, on June 18, 2019.
This especially highlights the work of lab alum Dr. Arif Nelson, and our upcoming paper in Current Opinion in Solid State and Materials Science which was written in collaboration with Ken Schweizer (MatSE, UIUC), Brittany Rauzan (Chemistry, UIUC), Ralph Nuzzo (Chemistry, UIUC), and Jan Vermant (Materials, ETH-Zürich).
Nature posted a Research Highlight of our collaborative work with Chemistry @ Illinois Prof. Steve Zimmerman and others.
Our work in JACS reports a new class of polymeric materials that rapidly degrade with an acid trigger.
The Ewoldt group contributions involved rheological measurement of degrading mechanical properties and mathematical modeling to infer molecular reaction rates from rheology.
The rapid self-degradation was found to be governed by an autocatalytic reaction, resulting in a governing differential equation known as the “logistic equation” (interestingly, this is also used for some human population growth models).
Miller et al., “Acid-triggered, acid-generating, and self-amplifying degradable polymers,”
Journal of the American Chemical Society (2019). http://doi.org/10.1021/jacs.8b07705
Congratulations to Rebecca! Our paper “Mechanically active materials in three-dimensional mesostructures,” in collaboration with Xin Ning, John Rogers, et al., is now online in Science Advances, and highlighted as a featured article.
The key idea is to combine advanced manufacturing and mechanics to integrate multiple, independently addressable piezoelectric thin-film actuators into complex, 3D mesostructures. Among the many possible uses, in this work we demonstrate the ability to measure viscosity and density of surrounding fluids.
The work is a tour de force of new theoretical derivations, first-of-their-kind model fitting to experiments, and new molecular insights for a transient polymer network.
We employ the concept of a parameterized continuous spectrum, which can dramatically reduce the number of fit parameters of a model, resulting in a model that is more credible, and with more certainty on parameter values for inferring molecular information.
The framework can be applied generally to a vast library of existing mathematical models (Corotational, Giesekus, etc.). The work demonstrates the potential of using weakly nonlinear oscillations, a developing area of characterization also known as medium-amplitude oscillatory shear (MAOS), to understand complex fluid and soft matter rheology.